Self-cleaning and droplet resistance cotton fabric

A recently conducted study focuses on hydrophobic cotton fabric synthesised via dispersion polymerisation from poly(glycidyl methacrylate) nanoparticles.

A sun sail as a symbolic image.
The modified cotton exhibited self-cleaning properties and various droplet resistance properties Image source: Antranias - Pixabay (symbol image).

During the study, researchers have developed a facile, efficient, and eco-friendly strategy for fabricating hydrophobic cotton fabrics using poly(glycidyl methacrylate) (PGMA) nanoparticles (NPs), which were synthesised via a radical-induced dispersion polymerisation technique. Interestingly, the long alkyl chain of octadecyl mercaptan provides a low surface free energy, while PGMA NPs act as anchors, forming covalent bonds with the surface of the cotton fabric, resulting in greater roughness. The covalent bonds, formed via the epoxy ring-opening reaction between the glycidyl groups of the PGMA NPs, react with the hydroxyl groups on the surface of the cotton fabric.

Promising applications in different fields

Mechanical characterisations suggested that the tear strength decreased for the modified fabric, whereas the stiffness was double that of neat cotton. The modified cotton fabric exhibited nano- and microscale roughness, which resulted in increased hydrophobicity, with a contact angle of 130°. The modified cotton exhibited self-cleaning properties and various droplet resistance properties, and thus has promising applications in different fields.

The study has been published in Progress in Organic Coatings, Volume 170, September 2022.

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