Superhydrophobic sponges for oil-water mixture separation

A recently conducted study portrays a self-stratifying coating that enables a facile fabrication of robust superhydrophobic sponges for oil-water mixture separation.

Revolutionizing oil spill cleanup, a study unveils a novel 3D interpenetrating network-coated sponge, created through a simple dipping technique, showcasing exceptional superhydrophobicity, robustness, and magnetic properties.
A 3D interpenetrating network structure coating, was used to prepare a robust, superhydrophobic and magnetic sponge. Image source: SusuMa - Pixabay (symbol image).

Superhydrophobic polymer sponges are a promising solution to the serious environmental crisis caused by oil spills in modern society, given their excellent sorption capacity and high selectivity, if designed well. However, realising such hydrophobic sponges in an eco-friendly, easy, and cost-effective way is still a challenging task, despite several reported methods. Researchers now report a facile approach to obtaining a superhydrophobic sponge using self-stratifying coating technology.

Good mechanical and thermal stability

The process briefly involves dip coating a pre-made commercial sponge in our prepared self-stratifying resin, followed by curing. The prepared superhydrophobic sponges showed excellent oil sorption capacity towards various organic solvents, with adsorptive capacity values ranging from ∼100 to 200 g/g and the capability to be reused >20 times with an adsorption retention capacity of above 95 % of the first cycle. In addition, the modified sponge presented good mechanical stability and thermal stability (up to 350 °C).

The study has been published in Progress in Organic Coatings, Volume 183, October 2023.

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