Inorganic additives and their impact on automotive coating systems
Researchers have systematically varied inorganic additives and and studied their impact on interfacial delamination processes of automotive coating systems.
Inorganic fillers incorporated in adhesives for the automotive industry enable both functional and mechanical tuning of adhesive properties. While integral effects of additives are well understood, the individual effects of single components and how they may lead to synergies as well as antagonistic effects remain unclear. Researchers have now systematically varied the concentration of CaO, CaCO3 and hydrophobic fumed SiO2 to understand individual and combined effects. For this purpose, the inorganic additives were mixed into a model formulation without inorganic additives and compared with a close to real application one-component epoxy adhesive, which also contained these fillers.
Improving beneficial and synergistic effects
Test results indicated that hydrophobic SiO2 can result in accelerated water uptake, although the opposite would be expected due to the more hydrophobic surface coating. In addition, blistering was observed on all galvanised steel (ZE) surfaces, while filiform corrosion was observed on all hot-dip galvanised Zn-Al-Mg steels (ZM). Cataplasma tests in oxygen-depleted and oxygen-rich atmospheres allowed to identify interfacial delamination processes. The results showed that CaO can cause osmotic blistering and accelerate the diffusion of water into the adhesive due to a local increase in pH near the hydrated CaO particles, while CaCO3 reduces water diffusion. However, coating defects may occur due to the addition of CaCO3, leading to increased cathodic blistering. A strategy for improving beneficial and synergistic effects is also discussed in the study.
The study has been published in Progress in Organic Coatings, Volume 173, December 2022.
