Hydrophilic ZIF-8 enhances reverse osmosis membrane performance

Researchers found that the use of tannic acid-modified ZIF-8 improves hydrophilicity and significantly increases the performance of reverse osmosis membranes.

Quelle: Vink Fan - Adobe.Stock
A nanocomposite osmosis membrane with hydrophilically modified ZIF-8 nanoparticles can improve performance. Quelle: Vink Fan - Adobe.Stock

The research proves that the integration of tannic acid-modified ZIF-8 into reverse osmosis membranes leads to a significant increase in permeability and improves salt retention.

Metal–organic frameworks (MOFs) are widely employed in designing nanocomposite membranes owing to their excellent performance and diversity. However, their inherent hydrophobicity limits their application in nanocomposite membranes. In order to improve the hydrophilicity of zeolitic imidazolate framework-8 (ZIF-8), tannic acid (TA) was utilized to etch-modify it, resulting in a TA-ZIF-8 nanostructure with a hydrophilic shell. TA-ZIF-8 was subsequently introduced into the aqueous phase and used to prepare a nanocomposite matrix reverse osmosis membrane through interfacial polymerization (IP).


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The prepared nanocomposite reverse osmosis membrane had a surface with good hydrophilicity and a pure water flux increased to 55.28 L m−2 h−1 (approximately 1.74 times). Additionally, the introduction of TA-ZIF-8 significantly enhanced the electronegativity of the membrane surface, and the nanoparticles were compatible with the polyamide layer, leading to a salt rejection rate of up to 99.5% for a NaCl solution with a concentration of 32000 ppm. These results indicate great potential for applying hydrophilically modified ZIF-8 to reverse osmosis membranes.

This research has been published in the Journal of Coatings Technology and Research, Volume 21, 2024.

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