Novel multifunctional WPU coatings
Multifunctional waterborne polyurethane (WPU) coatings with thermal insulation, matting, UV resistance and hydrophobicity are one of the targets of advanced materials manufacturing.
During a recent study, polymer hollow microspheres with polyhydroxy groups on the surface, called HM-OH, were prepared by emulsion polymerisation. Through TEM and SEM observations, it was confirmed that the HM-OH has a cavity (approximately 207 nm in diameter) with an average diameter of 726 nm. The relative content of the hydroxyl group on its surface is 9.1 %, and it has good dispersibility and thermal stability. A multifunctional low-gloss WPU nanocoating was prepared by grafting onto HM-OH, called WPU-g-HM. The emulsion stability test showed that WPU-g-HM basically solved the problem of blending incompatibility between HM and WPU, and the tensile strength and elastic modulus of WPU-g-HM reached their best values when the amount of HM-OH was 2.5 %.
Multifunctional WPU composite coating
UV–vis testing showed that the HM-OH made the prepared nanocoating have unique UV shielding properties. Furthermore, it was observed by SEM and AFM that the rough surface morphology of the nanocoating was the main reason for the decrease in the gloss of WPU-g-HM compared with WPU. The thermal conductivity of WPU-g-HM was 0.0347 W/(K·m), and the water contact angle was 100.3°, which indicated that the multifunctional WPU composite coating was successfully prepared.
The study has been published in Progress in Organic Coatings, Volume 182, September 2023.
Reading tip
The EC Tech Report Waterborne Protective Coatings gives you an extensive up-to-date bundle on protective coatings, focusing on water-borne solutions, with articles, videos and other content handpicked by the European Coatings Team. In addition to cutting-edge technical articles, the Tech Report is rounded off with valuable market insights and key fundamentals on water-borne protective coatings.
