Silica/methacrylate hybrids: Telomerisation versus RAFT polymerisation
For the synthesis of a polymer, researchers compared reversible addition fragmentation chain-transfer (RAFT) with telomerisation (TL), to investigate whether refining the polydispersity of polymethacrylate could lead to better and more tailorable properties.
Inorganic-organic co-networks prepared by a sol-gel method are a promising class of materials due to their unique physical and biological properties, especially when covalent bonds are formed between the networks. The polymer structure and composition can have a drastic effect on the synthesis and properties.
No difference in properties
3-(methoxysilyl)propyl methacrylate was used as a model and successfully synthesised by RAFT and TL using 2-cyano-2-propyl benzodithioate and thioglycerol as chain transfer agents, respectively. The polydispersity of the polymer had a significant effect on the sol-gel process with an increase in gelation time as the polydispersity decreased. Direct correlation was made between the gelation time and Mz, suggesting that the gelation of hybrids followed the percolation model. However, regarding the properties, it is a tie. No statistical difference in silica release and mechanical properties of the resulting hybrids was observed, regardless of the polydispersity of the polymer.
The study is published in: Polymer Chemistry, Issue 23, 2017.
